Sulfidation is a common concern at which location in a crude unit?

Sulfidation is a significant concern in the bottom of the crude unit's fractionating column due to the presence of higher concentrations of sulfur compounds and elevated temperatures that facilitate the formation of corrosive sulfide species. In this region, the conditions are conducive to sulfidation due to the combination of high temperatures and the presence of hydrogen sulfide, which is often found in crude oil.

As the crude oil is processed, heavier fractions with higher boiling points are separated as they move down through the column. The presence of moisture and sulfur in these heavier fractions interacts with the metal surfaces of the equipment, leading to corrosion through sulfidation, which can compromise the integrity of the pressure vessel. This type of corrosion is particularly aggressive and can result in significant material loss over time, making monitoring and inspection critical in this part of the unit.

Understanding the risks associated with sulfidation helps in implementing appropriate inspection techniques and materials management strategies to prolong the life of the equipment and maintain safe operational conditions.